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MATERIAL SAFETY DATA SHEET SECTION 1 PRODUCT AND COMPANY IDENTIFICATION PRODUCT: WeatherPro® Antifreeze/Coolant MSDS NUMBER: 94020L - 2 PRODUCT CODE(S): 94020, 9402006021 MANUFACTURER TELEPHONE NUMBERS SOPUS Products Spill Information: (877) 242-7400 SECTION 2 PRODUCT/INGREDIENTS INGREDIENTS CAS# CONCENTRATION Antifreeze/Coolant SECTION 3 HAZARDS IDENTIFICATION EMERGENCY OVERVIEWAppearance & Odor: Fluorescent green liquid. Mild odor. Health Hazards: NFPA Rating (Health, Fire, Reactivity): 2, 1, 0 Inhalation: In applications where vapors (caused by high temperature) or mists (caused by mixing or spraying) are created, breathingmay cause a mild burning sensation in the nose, throat and lungs.Eye Irritation: If irritation occurs, a temporary burning sensation, minor redness, swelling, and/or blurred vision may result. Skin Contact: May cause slight irritation of the skin. If irritation occurs, a temporary burning sensation and minor redness and/or swelling may result. Other adverse effects not expected from brief skin contact. Ingestion: May be harmful or fatal if swallowed. Contains ethylene glycol and/or diethylene glycol which are toxic when swallowed. A lethal dose for an adult is 1 ml per kilogram or about 4 ounces (1/2 cup). Severe kidney damage can occur as a result of ingestion. Ingestion may result in nausea, vomiting and abdominal cramps. Metabolic acidosis and cardiopulmonary effects can occur following ingestion. May cause Central Nervous System (CNS) depression. Other Health Effects: Refer to Section 11, Toxicological Information, for specific information on the following effects: Developmental Toxicity Primary Target Organs: The following organs and/or organ systems may be damaged by overexposure to this material and/or its components: Cardiovascular System, Kidney, Liver, Lungs Signs and Symptoms: May cause cardiopulmonary effects including rapid respiration and heartbeat, cyanosis and in severe cases, pulmonary edema and pneumonia. Early to moderate CNS depression may be evidenced by giddiness, headache, dizziness and nausea. In extreme cases, unconsciousness and death may occur. Kidney damage may be indicated by changes in urine output or appearance, pain upon urination or in the lower back or general edema (swelling from fluid retention). Liver damage may be indicated by loss of appetite, jaundice (yellowish skin and eye color), fatigue and sometimes pain and swelling in the upper right abdomen. Aggravated Medical Conditions: Pre-existing eye, skin, respiratory, liver and kidney disorders and may be aggravated by exposure to this product. SECTION 4 FIRST AID MEASURES Inhalation: Move victim to fresh air and provide oxygen if breathing is difficult. Get medical attention.Skin: Flush exposed area with water and follow by washing with soap if available. If skin irritation persists after washing, get medical advice. Eye: Flush eyes with plenty of water while holding eyelids open. Rest eyes for 30 minutes. If eye irritation persists, seek medical advice. Ingestion: DO NOT take internally. If swallowed, IMMEDIATELY contact a poison control center, emergency treatment center, or physician. If vomiting occurs spontaneously, keep head below hips to prevent aspiration of liquid into the lungs. Note to Physician: cardiopulmonary effects. For ETHYLENE GLYCOL POISONING, intravenous ethanol is a recognized antidotal treatment; other antidotal treatments also exist for ethylene glycol poisoning. SECTION 5 FIRE FIGHTING MEASURES Flash Point [Method]: 260 ºF/126.67 ºC [ Pensky-Martens Closed Cup] Extinguishing Media: Prevent run off from fire control or dilution from entering streams, sewers or drinking water supply. Use water fog, 'alcohol foam', dry chemical or carbon dioxide (CO2) to extinguish flames. Do not use a direct stream of water. Fire Fighting Instructions: Do not enter confined fire space without full bunker gear (helmet with face shield, bunker coats, gloves and rubber boots), including a positive pressure, NIOSH approved, self-contained breathing apparatus.
SECTION 6 ACCIDENTAL RELEASE MEASURES Protective Measures: May burn although not readily ignitable. Spill Management: Shut off source of leak if safe to do so. Dike and contain spill. FOR LARGE SPILLS: Remove with vacuum truck or pump to storage/salvage vessels. FOR SMALL SPILLS: Soak up residue with an absorbent such as clay, sand or other suitable material. Place in non-leaking container and seal tightly for proper disposal. Reporting: U.S. regulations require reporting releases of this material to the environment which exceed the reportable quantity to the National Response Center at (800)424-8802.
SECTION 7 HANDLING AND STORAGE Precautionary Measures:Do not ingest. Avoid prolonged or repeated contact with eyes, skin or clothing. Avoid breathing of vapors, fumes or mists. Use with adequate ventilation. Wash thoroughly after handling.Storage: Do not store in open or unlabeled containers. Store in a cool, dry place with adequate ventilation. Keep away from open flames and high temperatures. Container Warnings: Keep containers closed when not in use. Containers, even those that have been emptied, can contain explosive vapors. Do not cut, drill, grind, weld or perform similar operations on or near containers.
SECTION 8 EXPOSURE CONTROLS/PERSONAL PROTECTION Chemical Limit TWA STEL Ceiling Notation Ethylene Glycol ACGIH TLV 100 mg/m3 Ethylene Glycol OSHA PEL -50 ppmv 1989(revoked) Phosphoric acid ACGIH TLV 1 mg/m3 Phosphoric acid OSHA PEL -1 mg/m3 3 mg/m3 Exposure Controls Personal Protection Personal protective equipment (PPE) selections vary based on potential exposure conditions such as handling practices, concentration and ventilation. Information on the selection of eye, skin and respiratory protection for use with this material is provided below. Eye Protection: Chemical Goggles - If liquid contact is likely., or Safety glasses with side shields Skin Protection: Use protective clothing which is chemically resistant to this material. Selection of protective clothing depends on potential exposure conditions and may include gloves, boots, suits and other items. The selection(s) should take into account such factors as job task, type of exposure and durability requirements. Published literature, test data and/or glove and clothing manufacturers indicate the best protection is provided by: Neoprene, or Nitrile Rubber Respiratory Protection: If engineering controls do not maintain airborne concentrations to a level which is adequate to protect worker health, an approved respirator must be worn. Respirator selection, use and maintenance should be in accordance with the requirements of the OSHA Respiratory Protection Standard, 29 CFR 1910.134. Types of respirator(s) to be considered in the selection process include: For Mist: Air Purifying, R or P style NIOSH approved respirator. SECTION 9 PHYSICAL AND CHEMICAL PROPERTIES Appearance & Odor: Fluorescent green liquid. Mild odor.
SECTION 10 REACTIVITY AND STABILITY Stability: Thermal decomposition products are highly dependent on combustion conditions. A complex mixture of airborne solids, liquids and gases will evolve when this material undergoes pyrolysis or combustion. Acids, Aldehydes, Carbon Monoxide, Carbon Dioxide, Ketones and other unidentified organic compounds may be formed upon combustion.
SECTION 11 TOXICOLOGICAL INFORMATION Acute Toxicity TEST Result OSHAMaterial Tested Carcinogenicity Classification Chemical Name NTP IARC ACGIH OSHA
Developmental Toxicity Kidney Liver Lungs Whole Animal SECTION 12 ECOLOGICAL INFORMATION Environmental Fate:
SECTION 13 DISPOSAL CONSIDERATIONS RCRA Information:
SECTION 14 TRANSPORT INFORMATION US Department of Transportation Classification This material is not regulated under 49 CFR if in a container of 119 gallon capacity or less. If shipped in a container of over 119 gallon capacity then the DOT information must be accompanied with RQ notation, or, an otherwise 'Not Regulated' product will be classified as Environmentally Hazardous (solid/liquid) N.O.S., Class 9, Packing group III unless the product qualifies for the petroleum exemption (49 CFR 171.8). Hazardous Substance/Material RQ: Ethylene glycol / 5209.3481 lbs International Air Transport Association Hazard Class/Division: 9 (Miscellaneous) Identification Number: UN3082 Packing Group: III Proper Shipping Name: Environmentally Hazardous Substance, Liquid, N.O.S. Technical Name(s): Ethylene Glycol International Maritime Organization Classification Hazard Class/Division: 9 (Miscellaneous) Identification Number: UN3082 Packing Group: III Proper Shipping Name: Environmentally Hazardous Substances, Liquid, N.O.S. Technical Name(s): Ethylene Glycol
SECTION 15 REGULATORY INFORMATION OSHA Classification: Comprehensive Environmental Release, Compensation & Liability Act (CERCLA): Ozone Depleting Substances (40 CFR 82 Clean Air Act): Superfund Amendment & Reauthorization Act (SARA) Title III: SARA Hazard Categories (311/312): Immediate Health Delayed Health Fire Pressure Reactivity SARA Toxic Release Inventory (TRI) (313): Toxic Substances Control Act (TSCA) Status: Other Chemical Inventories: State Regulation The following chemicals are specifically listed by individual states; other product specific health and safety data in other sections of the MSDS may also be applicable for state requirements. For details on your regulatory requirements you should contact the appropriate agency in your state. New Jersey Right-To-Know Chemical List: Pennsylvania Right-To-Know Chemical List:
SECTION 16 OTHER INFORMATION Revision#: 2Revision Date: 11/16/2004 Revisions since last change (discussion): This Material Safety Data Sheet (MSDS) has been newly reviewed to fully comply with the guidance contained in the ANSI MSDS standard (ANSI Z400.1-1998). We encourage you to take the opportunity to read the MSDS and review the information contained therein.
SECTION 17 LABEL INFORMATION READ AND UNDERSTAND MATERIAL SAFETY DATA SHEET BEFORE HANDLING OR DISPOSING OF PRODUCT. THIS LABEL COMPLIES WITH THE REQUIREMENTS OF THE OSHA HAZARD COMMUNICATION STANDARD (29 CFR 1910.1200) FOR USE IN THE WORKPLACE. THIS LABEL IS NOT INTENDED TO BE USED WITH PACKAGING INTENDED FOR SALE TO CONSUMERS AND MAY NOT CONFORM WITH THE REQUIREMENTS OF THE CONSUMER PRODUCT SAFETY ACT OR OTHER RELATED REGULATORY REQUIREMENTS. PRODUCT CODE(S): 94020, 9402006021 WeatherPro® Antifreeze/Coolant WARNING! MAYBE HARMFUL OR FATAL IF SWALLOWED. MAY CAUSE ACIDOSIS, CARDIOPULMONARY AND KIDNEY EFFECTS. MAY CAUSE CENTRAL NERVOUS SYSTEM DEPRESSION. The following organs and/or organ systems may be damaged by overexposure to this material and/or its components. MAY CAUSE DAMAGE TO: Cardiovascular System, Kidney, Liver, Lungs Refer to Section 11, Toxicological Information, for specific information on the following effects: Developmental Toxicity Precautionary Measures: Avoid prolonged or repeated contact with eyes, skin and clothing. Avoid breathing of vapors, fumes, or mist. Use only with adequate ventilation. Keep container closed when not in use. Wash thoroughly after handling. FIRST AID Inhalation: Move victim to fresh air and provide oxygen if breathing is difficult. Get medical attention. Skin Contact: Flush exposed area with water and follow by washing with soap if available. If skin irritation persists after washing, get medical advice. Flush eyes with plenty of water while holding eyelids open. Rest eyes for 30 minutes. If eye irritation persists, seek medical advice. Ingestion: DO NOT take internally. If swallowed, IMMEDIATELY contact a poison control center, emergency treatment center, or physician. If vomiting occurs spontaneously, keep head below hips to prevent aspiration of liquid into the lungs. FIRE In case of fire, Use water fog, 'alcohol foam', dry chemical or carbon dioxide (CO2) to extinguish flames. Do not use a direct stream of water. SPILL OR LEAK Dike and contain spill. FOR LARGE SPILLS: Remove with vacuum truck or pump to storage/salvage vessels. FOR SMALL SPILLS: Soak up residue with an absorbent such as clay, sand or other suitable material. Place in non-leaking container and seal tightly for proper disposal. CONTAINS: Ethylene Glycol, 107-21-1; Deionized Water, 7732-18-5; Phosphoric acid, 7664-38-2 NFPA Rating (Health, Fire, Reactivity): 2, 1, 0TRANSPORTATION US Department of Transportation Classification This material is not regulated under 49 CFR if in a container of 119 gallon capacity or less. If shipped in a container of over 119 gallon capacity then the DOT information must be accompanied with RQ notation, or, an otherwise 'Not Regulated' product will be classified as Environmentally Hazardous (solid/liquid) N.O.S., Class 9, Packing group III unless the product qualifies for the petroleum exemption (49 CFR 171.8). Hazardous Substance/Material RQ: Ethylene glycol / 5209.3481 lbs CAUTION: Misuse of empty containers can be hazardous. Empty containers can be hazardous if used to store toxic, flammable, or reactive materials. Cutting or welding of empty containers might cause fire, explosion or toxic fumes from residues. Do not pressurize or expose to open flames or heat. Keep container closed and drum bungs in place. Name and Address SOPUS Products P.O. Box 4427 Houston, TX 77210-4427 ADMINISTRATIVE INFORMATION MANUFACTURER ADDRESS: THE INFORMATION CONTAINED IN THIS DATA SHEET IS BASED ON THE DATA AVAILABLE TO US AT THIS TIME, AND IS BELIEVED TO BE ACCURATE BASED UPON THAT: IT IS PROVIDED INDEPENDENTLY OF ANY SALE OF THE PRODUCT, FOR PURPOSE OF HAZARD COMMUNICATION. IT IS NOT INTENDED TO CONSTITUTE PRODUCT PERFORMANCE INFORMATION, AND NO EXPRESS OR IMPLIED WARRANTY OF ANY KIND IS MADE WITH RESPECT TO THE PRODUCT, UNDERLYING DATA OR THE INFORMATION CONTAINED HEREIN. YOU ARE URGED TO OBTAIN DATA SHEETS FOR ALL PRODUCTS YOU BUY, PROCESS, USE OR DISTRIBUTE, AND ARE ENCOURAGED TO ADVISE THOSE WHO MAY COME IN CONTACT WITH SUCH PRODUCTS OF THE INFORMATION CONTAINED HEREIN. TO DETERMINE THE APPLICABILITY OR EFFECT OF ANY LAW OR REGULATION WITH RESPECT TO THE PRODUCT, YOU SHOULD CONSULT WITH YOUR LEGAL ADVISOR OR THE APPROPRIATE GOVERNMENT AGENCY. WE WILL NOT PROVIDE ADVICE ON SUCH MATTERS, OR BE RESPONSIBLE FOR ANY INJURY FROM THE USE OF THE PRODUCT DESCRIBED HEREIN. THE UNDERLYING DATA, AND THE INFORMATION PROVIDED HEREIN AS A RESULT OF THAT DATA, IS THE PROPERTY OF SOPUS PRODUCTS AND IS NOT TO BE THE SUBJECT OF SALE OR EXCHANGE WITHOUT THE EXPRESS WRITTEN CONSENT OF SOPUS PRODUCTS. 43716-11566-100R-11/16/2004 |
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